High Quality Tridentate Ligand Tripyridyl 1148-79-4 Available with Competitive Price

High Quality Tridentate Ligand Tripyridyl 1148-79-4 Available with Competitive Price

Name: 2,2′:6′,2″-Terpyridine

Other name: tripyridyl; Terpyridine; 2,2':6',2"-Terpyridyl; 2,6-Bis(2-pyridyl)pyridine

CAS: 1148-79-4

EINECS: 214-559-5

MW: 233.27

Product Details

Name: 2,2′:6′,2″-Terpyridine

Other name: tripyridyl; Terpyridine; 2,2':6',2"-Terpyridyl; 2,6-Bis(2-pyridyl)pyridine

CAS: 1148-79-4

EINECS: 214-559-5

MF: C15H11N3 

MW: 233.27

MP: 90-93oC

Appearance: light-yellow to white powder

Purity: 98%min.

Package: 25g, 100g, 500g, 1Kg, bulk package

 

Terpyridine (2,2';6',2"-terpyridine, often abbreviated to Terpy or Tpy) is a heterocyclic compound derived from pyridine. It is a white solid that is soluble in most organic solvents. The compound is mainly used as a ligand in coordination chemistry..

Terpyridine was first synthesized by G. Morgan and F. H. Burstall in 1932 by the oxidative coupling of pyridines. This method, however, proceeded in low yields. More efficient syntheses have since been described, mainly starting from 2-acetylpyridine.

Terpyridine is a tridentate ligand that binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings. Terpyridine forms complexes with most transition metal ion as do other polypyridine compounds, such as 2,2'-bipyridine and 1,10-phenanthroline. Complexes containing two terpyridine complexes, i.e. [M(Terpy)2]n+ are common. They differ structurally from the related [M(Bipy)3]n+ complexes in being achiral.

Terpyridine complexes, like other polypyridine complexes, exhibit characteristic optical and electrochemical properties: metal-to-ligand charge transfer (MLCT) in the visible region, reversible reduction and oxidation, and fairly intense luminescence.

Because they are pi-acceptors, terpyridine and bipyridine tend to stabilize metals in lower oxidation states. For instance in acetonitrile solution, it is possible to generate the [M(Terpy)2]+ (M = Ni, Co).



Inquiry